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By Shane Lasley
Mining News 

Tin – Alaska's gateway critical mineral

Getting hooked on tin deposits leads to other critical minerals

 

Last updated 7/20/2019 at 7:57am

Getting hooked on Cassiterite deposits leads to other critical minerals

Lubor Ferenc; Wikimedia Commons

A pair of 10th Century BC bronze swords found in Switzerland. An alloy of tin and copper, bronze was a critical metal for weapons and tools during the Bronze Age, an era that spans more than 2,000 years of human history.

With more than 100 known tin occurrences, Alaska is considered the best place in America to establish a domestic source of this critical alloy metal that has defined human progress since the dawn of the Bronze Age.

"Today, Alaskan tin deposits are known to be widespread, occurring from the central Alaska Range north to the Brooks Range and across Interior Alaska ... Southwest Alaska and the Seward Peninsula," according to the 1997 publication, Mineral Deposits of Alaska.

And where an explorer finds tin in Alaska, he is likely to find himself dabbling in at least a few of the other minerals critical to the strategic and economic wellbeing of the United States.

In fact, more than a dozen metals considered critical by the U.S. Geological Survey – beryllium, bismuth, chromium, fluorspar, gallium, indium, manganese, niobium, platinum group metals, rare earth elements, scandium, strontium, tantalum, tungsten and vanadium – have been found associated with the placer and lode tin occurrences across the state.

Eons of criticality

Primarily associated with cans, cups and roofs, tin does not spark the imagination with images of a strategic metal. The Pentagon, however, sees the United States' heavy reliance on foreign countries for this fundamental metal as a detriment to national security.

"In a congressionally mandated U.S. Department of Defense study of strategic minerals published in 2013, tin was shown to have the greatest shortfall amount (insufficient supply to meet demand measured in monetary terms – US$416 million) in a list of strategic minerals, and more than twice the shortfall amount of the next strategic mineral, antimony (US$182 million)," USGS penned in Critical Mineral Resources of the United States, a report published late in 2017.

Tin's provenance as a critical mineral, however, dates back eons before the formation of the United States.

In fact, this metal's strategic importance can be traced at least 5,500 years, when early human civilizations discovered that mixing a little tin with copper created bronze, an alloy that produced much more durable weapons and tools than those cast from copper alone.

The first civilizations to discover this cutting-edge metallurgical technology had a strategic and economic advantage over their counterparts. This edge was so powerful that we now consider the Bronze Age one of the most important epochs of human history, an era that spans more than 2,000 years.

Not unlike our Bronze Age forebearers, we continue to almost exclusively use tin in alloys, mixtures that keep tin on the list of critical minerals.

In 2018, the United States consumed roughly 101.3 million pounds of tin for bronze, brass and other alloys; cans and containers; solder; bearing surfaces and other applications.

None of this tin was mined in the U.S. Instead, roughly 78 percent America's tin supply was imported from foreign countries –Indonesia (23 percent), Malaysia (23 percent), Peru (22 percent) and Bolivia (17 percent) are top tin suppliers – and the balance was the product of recycling.

"Tin has not been mined or smelted in the United States since 1993 and 1989, respectively," USGS penned in its Mineral Commodity Summaries 2019 publication.

This complete dependence on foreign sources for new supply, coupled with the alloying metal's importance to both manufacturing and defense, is the reason both the Pentagon and USGS consider tin critical to the United States.

The average paid for this tin during 2018 was around US$9.30/lb but the price of the alloying metal dropped sharply to US$6.00/lb in March.

Based on the average Platts Metals Week New York dealer price for tin, the estimated value of imported refined tin was $703 million, and the estimated value of tin recovered from old scrap domestically was $213 million," USGS wrote on the 2018 tin sector in the United States.

Around Tin City

Unlike most metals and minerals, where hardrock mining dominates large scale production, most of the world's supply of tin comes from placer mining of cassiterite, a tin mineral, from alluvial deposits that have eroded from the lode source.

"Placer deposits have traditionally been an important source of tin; in 2012, they accounted for about 70 percent of the world output of cassiterite concentrates," USGS inked in its critical minerals report.

While there have not been any notable placer tin deposits identified in the Lower 48 states, they are widespread across Alaska.

In fact, the western tip of the Seward Peninsula has alluvial deposits so rich in cassiterite that early prospectors who flocked to the area during the gold rush days established Tin City, a small mining town near Cape Mountain and about 90 miles northwest of Nome, in 1904.

Placer mining of Cape Creek, which drains the mountain rising to the northwest of Tin City, produced an estimated 3.3 million pounds of tin, according to the USGS. The largest known chunk of cassiterite recovered during placer mining of Cape Creek weighed 142 lbs.

While Tin City and the mines it hoped to support were short-lived, this minerals-rich area of western Alaska still hosts rich placer and lode tin deposits.

Other tin prospects found near Cape Mountain include Lost River and Potato Mountain.

Kougarok, located about 90 miles east of Tin City, is another promising lode tin deposit on the Seward Peninsula.

Work in the 1980s estimated a portion of the tin-bearing granites there hosts some 6 million lb of tin in 240,000 tons of historical resource averaging 1.3 percent tin. Some of the tin deposits at Kougarok have an appreciable amount of beryllium, tungsten, fluorspar, niobium and tantalum, all on the USGS list of critical minerals.

Interior gold miners' nuisance

Tin has also been produced from placer deposits in Interior Alaska, primarily as a product of gold mining.

The tin in at least one Interior Alaska stream – Boulder Creek in the Circle Mining District – is so prolific that it plugs the placer recovery plant, making it a nuisance for miners attempting to recover the gold from this stream about 125 road miles northeast of Fairbanks.

While there has been no systematic testing of the placer tin content, a miner attempting to recover the gold in a particularly tin-enriched portion of the creek estimated the gravel contained more than 2 lb of cassiterite, a primary tin mineral, per yard.

An investigation carried out by James Barker for the U.S. Bureau of Mines indicates that the lode source of this tin mineralization is very close.

"Cassiterite occurs as fresh unweathered crystals up to 3/8 of an inch long, some of which are attached to gangue rock," he wrote in a 1979 report. "Tin is particularly concentrated in the coarser size fractions. The gold is also quite fresh, occurring primarily as thin irregular flakes. The balance of the concentrate consists of rounded nuggets of hematite, magnetite, and scheelite."

Scheelite is a mineral of tungsten, which the USGS also considers critical.

One sample of fresh granite collected by Barker near Boulder Creek returned 20 parts per million tin and 22 ppm tungsten. The sample also contained gold and molybdenum.

Tin and tungsten have been found in many of the other creeks in the region – Bedrock, Deadwood, Independence and Half Dollar, to name a few.

The Lime Peak and Mount Prindle areas to the west of the Circle Hot Springs granitic intrusive feeding these creeks also has tin and tungsten mineralization.

Cassiterite a Tofty by-product

The most widely known placer tin deposits in Interior Alaska, however, are found along the Tofty tin belt, a 12-mile-long area of tin- and gold-bearing gravels in the Manley Hot Springs district, another gold-rich area of Interior Alaska.

While it is unclear how much tin has been recovered from the streams of this mining district about 90 miles northwest of Fairbanks, much like the area around Tin City, gold miners were recovering placer cassiterite at the dawn of the 20th Century.

"Gold mining in the district developed rapidly, and as the productive area in the vicinity of Tofty increased it was found that tin and gold were generally associated and that the richer concentrations of the two minerals were generally coincident," Henry Eakin wrote in a 1914 report, Tin Mining in Alaska.

Like Boulder Creek, the high tin concentrations plugging the riffles of their sluice boxes was a nuisance to the early miners attempting to recovery placer gold in the Hot Springs District. These miners, however, soon decided to try to cash in on the cassiterite piling up on their claims.

In 1911, about 1,200 pounds of tin concentrates accumulated from cleaning out the sluice boxes were shipped to Singapore for processing.

"The ore was found to be of high quality, and the returns from the small shipment directed attention for the first time to the possible value of tin as a by-product," Eakin penned.

And in 1914, roughly 48 tons of tin was shipped from the gold mines in the Hot Springs district.

Over the years since, various miners have recovered cassiterite as a by-product of gold mining.

A search for the lode source of the tin found in the stream did not turn up appreciable amounts of cassiterite but samples collected by the Alaska Division of Geological and Geophysical Surveys did find intriguing quantities of other minerals now considered critical by the USGS.

The host of critical minerals – bismuth, chromium, gallium, manganese, niobium, rare earth elements, scandium, strontium, tantalum and vanadium – have been identified in samples collected from the Manley Hot Springs district.

About 60 miles north of the cassiterite-bearing streams at Tofty, Ucore Rare Metals has found that the rare earths-rich placer deposits on its Ray Mountains property contain appreciable amounts of tin and other critical minerals.

Concentrates from gravity separation of placer samples collected at Ray Mountains returned up to 50 percent tin; 10 percent rare earths; and 0.01 to 1 percent tungsten, tantalum and niobium.

"The Ray Mountains project has select areas rivaling HREE (heavy rare earth element) content at our Bokan property, and the remarkable advantage of collateral tin, niobium and tantalum mineralization which enhances prospective values per ton." Ucore President and CEO Jim McKenzie said, referring to the company's Bokan Mountain rare earth property on Prince of Wales Island in Southeast Alaska.

A definitive lode source of the 100-meter-deep critical mineral-bearing gravels at Ray Mountains has yet to be identified.

Hawley's Alaska Range discoveries

One place where the lode source of tin has been identified is in the Alaska Range south of Fairbanks.

Coal Creek, a 2,400-acre property just west of the Parks Highway roughly halfway between Anchorage and Fairbanks, is one such property that has garnered some interest in recent years.

Discovered by Charles Hawley in 1972, Coal Creek was staked for its tin-silver potential by Houston Oil and Minerals in 1980. Over the ensuing five years, this exploration company carried out exploration programs that included 5,240 meters of drilling in 42 holes.

A preliminary resource calculated for Houston Oil and Minerals in 1982, estimated the drilled portion of the Coal Creek deposit contained roughly 4.8 million metric tons averaging 0.27 percent tin, according to data published by the U.S. Geological Survey.

While the resource does not meet the rigor of current reporting standards, sampling of core stored at the Alaska Geologic Materials Center in Anchorage and four holes drilled by Brett Resources in 2006 confirms the tin-silver potential of this easily accessible property.

Highlights from the drilling include: 9.4 meters averaging 0.41 percent tin, 18.21 grams per metric ton silver and 0.81 percent zinc; and 9.3 meters averaging 0.45 percent tin, 11.95 g/t silver and 0.29 percent zinc.

Tungsten and gold also have been identified at Coal Creek. Choice grab samples collected from the property in 1990 turned up 720 g/t tungsten, 65 g/t silver, 0.5 g/t gold and 4.86 percent zinc.

Like the other tin deposits in Alaska, Coal Creek has tin-bearing neighbors enriched with a suite of other critical minerals.

Ohio Creek, another Hawley discovery to the northwest, has yielded a wide variety of minerals and metals.

A study completed by the U.S. Bureau of Mines in the 1980s identified wodginite, a manganese-tin-niobium oxide; tungsten; gold; silver; palladium, a platinum group metal; and a suite of rare earths in the area.

As part of Alaska's Strategic and Critical Minerals Assessment project, the Alaska Division of Geological & Geophysical Surveys re-analyzed rock samples from the earlier study. A report published by DGGS in 2014 confirmed the earlier findings.

Strongbow Exploration Inc. acquired Coal Creek and commissioned a technical report on the property in 2015 but has not followed up with any significant exploration there.

Tin-rich Kuskokwim Mountains

The Kuskokwim Mountains of Southwest Alaska is another place known for its tin potential and Strongbow also holds a cassiterite-bearing property there.

This property, Sleitat, was explored by Cominco (now Teck Resources) in the 1980s, which discovered two zones of tin mineralization.

One hole drilled by Cominco cut 3.1 meters of 12.55 percent tin and 197.5 g/t silver. The overall deposit evaluated by the nine holes drilled by the company was much lower grade.

Using the information from Cominco drilling and surface sampling, the Bureau of Mines estimated the area of known mineralization at Sleitat encompassed roughly 25.9 million metric tons averaging between 0.22 and 0.37 percent tin, 17 g/t silver and 0.04 percent tungsten.

In a 2015 technical report for Strongbow, Alaska Earth Sciences recommended airborne geophysical surveys that could help target future drilling at Sleitat.

Three other prospects in the Kuskokwim region of Southwest Alaska – Bismarck Creek, Win and Won – are also prospective for tin.

Chip-channel samples collected at Bismarck Creek, about 40 miles southwest of McGrath, returned up to 2.8 percent tin, 63 g/t silver, 590 g/t copper, more than 1 percent zinc and 0.03 percent antimony. Selected samples are also reported to run up to 0.01 percent indium, another USGS critical mineral.

Based on extensive surface sampling, it is estimated that the Bismarck Creek deposit contains 500,000 metric tons averaging 0.14 percent tin and 47.8 g/t silver.

Sampling at Win, located about 20 miles north of McGrath, yielded several high-grade samples of polymetallic mineralization. One 7.75-foot channel sample collected by the Bureau of Mines in 1992 returned 18.82 oz/t silver and 6.97 percent tin.

Other samples from Win ran as high as 94.63 oz/ton silver, 46.4 percent tin, 926 ppm bismuth, 0.36 percent copper, 0.17 percent niobium and 5 percent antimony.

Despite the high-grade metals found at Win, no drilling is reported for this prospect.

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James Barker

This dredge is a reminder of the early 20th Century placer tin mining carried out in the Lost River area in western Alaska..

The tin-bearing veins at the Won prospect, however, have been drilled.

Two holes drilled by Anaconda Minerals Company cut up to 6.9 percent tin and 3.3 oz/ton silver, along with antimony, lead, arsenic, copper, and tungsten over unknown widths.

The authors of a 2004 USGS report, Metallogenesis and Tectonics of the Russian Far East, Alaska, and the Canadian Cordillera, the Win and Won prospects "contain some of the most important tin-polymetallic resources in the Kuskokwim Mineral Belt and perhaps in all of Alaska."

Like the other tin-enriched regions of the state, a winning search for tin in Southwest Alaska will likely lead to the discovery of a suite of the minerals the USGS considers critical to America's security and economic well-being. This makes tin an ideal gateway metal for anyone exploring the Last Frontier's rich critical minerals potential.

Metal Tech News - Discovering the elements of innovationGetting hooked on Cassiterite deposits leads to other critical mineralsMetal Tech News - Discovering the elements of innovationGetting hooked on Cassiterite deposits leads to other critical mineralsMetal Tech News - Discovering the elements of innovation

 

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